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The mixture that forms maximum boiling azeotrope is
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By Expert Faculty of Sri Chaitanya
a
heptane + octane
b
water + nitric acid
c
ethanol + water
d
acetone+carbon disulphide.
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Correct option is B
Maximum boiling azeotropes are formed by those solutions which show negative deviations from Raoult's law. H2O and HNO3 mixture shows negative deviations.Mineral acids when dissolved in water get ionised. Strong ion - dipole attractions develop between mineral acid and water molecules.
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