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Q.

A mixture of 2.3 g formic acid and 4.5 g oxalic acid is treated with conc. H2SO4. The evolved gaseous mixture is passed through KOH pellets. Weight (in g) of the remaining product at STP will be

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Detailed Solution

KOH pellets absorbs CO2(g) obtained but not COH2SO4 absorbs water vapour.CO obtained from Formic acid HCOOH →CO(g) +H2O(g)46 gm of formic acid gives 28 gm of CO 2.3 gm gives =2.346×28=1.4 gm(COOH)2→CO(g) +CO2(g) +H2O(g)CO from Oxalic acid90 gm of Oxalic acid gives 28 gm of CO4.5 gm gives =4.590×28=1.4 gmTotal weight =1.4+1.4 = 2.8 gm
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