A mixture of NO2 and N2O4 has a vapour density of 38.3 at 300 K. What is the number of moles of NO2 in 100 g of the mixture ?
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a
0.043
b
4.4
c
3.4
d
0.437
answer is D.
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Detailed Solution
Molecular weight of mix. = 2 x V.D =2 x 38.3 = 76.6 gWeight of NO2 = xSo that weight of N2O4 = 100 - xHence, x46+100−x92 = 10076.6=2x+100−x92 = 10076.6 x = 20.10 g the number of moles of NO2 = 20.1046=0.437