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Q.

A mixture of two moles of carbon monoxide and one mole or oxygen, in a closed vessel is ignited to convert the carbon monoxide to carbon dioxide. If ∆H is the enthalpy change and ∆E is the change in internal energy, then

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a

ΔH>ΔE

b

ΔH<ΔE

c

ΔH=ΔE

d

The relationship depends on the capacity of the vessel

answer is B.

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Detailed Solution

Formation of CO2 and CO is an exothermic reaction: heat is evolved from the system. i.e.  energy is lowered. Thus. exothermic reactions occur spontaneously on account of decrease in enthalpy of system Thus. ΔE>ΔH.
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A mixture of two moles of carbon monoxide and one mole or oxygen, in a closed vessel is ignited to convert the carbon monoxide to carbon dioxide. If ∆H is the enthalpy change and ∆E is the change in internal energy, then