A, mixture x containing 0.02 mol of CoNH35SO4Br and 0.02 mol of CoNH35BrSO4 was prepared in 2 L of solution.1 L of mixture X+excess AgNO3 → Y1 L of mixture X+excess BaCl2 → ZThe number of moles of Y and Z are
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a
0.01, 0.01
b
0.02, 0.01
c
0.01, 0.02
d
0.02, 0.02
answer is A.
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Detailed Solution
A mixture X containing 0.02 mol of CoNH35SO4Br and 0.02 mol of CoNH35BrSO4 was prepared in 2 L of solution. This means 1 L of the mixture contains 0.01 mol of CoNH35SO4Br 0.01 mol of CoNH35BrSO41 L of mixture X+excess AgNO3 → 0.01 mol AgBr1 L of mixture X+excess BaCl2 → 0.01 mol BaSO4This is according to the following reactions taking place :CoNH35SO4Br + AgNO3 → CoNH35SO4 NO3+AgBr↓CoNH35BrSO4 + BaCl2 → CoNH35Br Cl2+BaSO4↓