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Q.

Mixture X of 0.02 mole of CoNH35SO4Br and 0.02 mole of CoNH35BrSO4 was prepared in 2 litre of solution :1 litre of mixture X + excess of AgNO3→Y1 litre of mixture X + excess of BaCl2→ZNumber of moles of Y and Z respectively are :

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a

0.01, 0.02

b

0.02, 0.01

c

0.01, 0.01

d

0.02, 0.02

answer is C.

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Detailed Solution

1 litre of mixture X contains 0.01 mole of CoNH35SO4Br and 0.01mole of CoNH35BrSO4. 1 litre of mixture X+ excess of AgNO3→AgBr↓(Y) pale yellow ppt. . (0.01 moles of AgBr ). 1 litre of mixture X+ excess of BaCl2→BaSO4↓(Z)0.01 moles of BaSO4
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