Mixture ‘x’ of 0.02 moles of CoNH35SO4Br and0.02 moles of CoNH35BrSO4 was prepared in 2 lit solution1 lit of mixture ‘x’ + excess AgNO3→Y1 lit of mixture ‘x’ + excess BaCl2→ZThen the number of moles of ‘Y’ and ‘Z’ respectively are

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0.01, 0.02

0.02 ,0.01

0.01 ,0.01

0.02 ,0.02

answer is C.

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Detailed Solution

0.01 mole CoNH35SO4Br with AgNO3solution gives 0.01 moles of AgBrY 0.01 mole CoNH35BrSO4 with BaCl2 solution gives 0.01 moles of BaSO4Z

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