Q.

54 ml of liquid ‘A’  is mixed with 54 ml of liquid ‘B’. The volume of the mixture formed is 108 ml. The two liquids are most likely to be

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a

C6H6+C6H5CH3

b

C6H5OH+C6H5NH2

c

CH3COCH3+CS2

d

C2H5OH+H2O

answer is A.

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Detailed Solution

VA=54 ml ; VB=54 ml ; Vmix=108 ml ; ∆Vmix= 0 ; Magnitude of A-B interactions is equal to magnitude of A-A and B-B interactions; Solution is ideal; Mixture of benzene and toulene is an ideal solution;
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