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500 mL of 0.2 M KOH and 500 mL of 0.2 M HCl are mixed. The rise in temperature is T1 . the experiment is repeated using 250 mL of each solution and the rise in temperature is T2 . Which of the following is true?

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a

T1=T2

b

T1=2T2

c

T1=4T2

d

T2=9T1

answer is A.

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Detailed Solution

Suppose heat evolved in first case = Q1Heat evolved in second case = Q2 Then, Q2=12Q1 but Q1=1000T1 and Q2=500T2∴500T2=121000T1, i.e., T1=T2

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500 mL of 0.2 M KOH and 500 mL of 0.2 M HCl are mixed. The rise in temperature is T1 . the experiment is repeated using 250 mL of each solution and the rise in temperature is T2 . Which of the following is true?