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Q.

100 mL of 0.8 M NaOH are used to neutralise 100 mL solution obtained by passing 2.70 g SO2Cl2  in water. Select the correct statement.

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a

The solution of SO2Cl2 has 0.2 M H2SO4 and 0.4 M HCl

b

The volume ratio of NaOH used for H2SO4 and HCI is 1:2

c

The volume ratio of NaOH used for H2SO4 and HCI is 1:1

d

Molarity of SO2Cl2 solution is 0.1 M

answer is A.

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Detailed Solution

SO2Cl2=2.70×1000135×100=0.2MSO2Cl2100×0.2=200   +   2H2O    →   H2SO4 020  + 2HCl040 ∴MH2SO4=20100;MHCl=40100∴NH2SO4=0.4 and NHCl=0.4
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