Q.
20 ml of a mixture of CO and H2 were mixed with excess of O2 and exploded and cooled. There was a volume contraction of 18 mL. All volume measurements corresponds to room temperature (27°C) and one atmospheric pressure. Determine the volume ratioV1:V2 of CO and H2 in the original mixture.
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a
1:2
b
3 : 2
c
2:3
d
4 : 1
answer is B.
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Detailed Solution
COx+12O2x/2⟶CO2x H2(20−x)+12O220−x2⟶H2O(l); Volume contraction= V.R-V.P=(x+x2-x)+[20-x+12(20-x)-0] 18=x2+3(20-x)2x=12mL=COH2=8mLVCO:VH2=12:8=3:2
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