250 mL of a waste solution obtained from the workshop of a goldsmith contains 0.1 M AgNO3 and 0.1 M AuCl. The solution was electrolyzed at 2 V by passing a current of 1 A for 15 minutes. The metal / metals electrodeposited will be:EAg+/Ag0=0.80V, EAu+/Au0=1.69V
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a
only silver
b
silver and gold in equal mass proportion
c
silver and gold in proportion to their atomic weights
d
only gold
answer is C.
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Detailed Solution
WAwWAg=ZAv(Q)ZAg(Q)= Atomic mass of Gold Valencyof gold Atomicmass of silver Valency of silver