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Q.

250 mL of a waste solution obtained from the workshop of a goldsmith contains 0.1 M AgNO3 and 0.1 M AuCl. The solution was electrolyzed at 2 V by passing a current of 1 A for 15 minutes. The metal / metals electrodeposited will be:EAg+/Ag0=0.80V,  EAu+/Au0=1.69V

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a

only silver

b

silver and gold in equal mass proportion

c

silver and gold in proportion to their atomic weights

d

only gold

answer is C.

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Detailed Solution

WAwWAg=ZAv(Q)ZAg(Q)= Atomic mass of Gold  Valencyof gold  Atomicmass of silver  Valency of silver
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