Q.

Mn(CO)4NO is diamagnetic because :

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a

Mn metal is diamagnetic in free state

b

Mn is in + 1 oxidation state in this complex

c

NO is present as positive ligand

d

All of the above

answer is C.

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Detailed Solution

Mn(CO)+14NO−:Paramagnetic due to presence of unpaired e−s in NO− Mn(CO)4NO+:No unpaired e−either on ligands or on Mn hence it is diamagnetic
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Mn(CO)4NO is diamagnetic because :