Q.
0.1 mol of CH3NH2 (Kb = 5 x 10-4) is mixed with 0.08 mol of HCI and diluted to 1 L. What will be the H+ concentration in the solution?
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a
8×10−2M
b
8×10−11M
c
1.6×10−11M
d
8×10−5M
answer is B.
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Detailed Solution
CH3NH2+H+Cl−⇌CH3NH3+Cl− Initial 0.1 0.08 - Final 0.02 - 0.08 MCH3NH2+H2O⇌CH3NH3++OH− Kb=CH3NH3+OH−CH3NH2 5×10−4=(0.08)OH−(0.02) OH−=1.25×10−4M H+=KwOH−=1×10−141.25×10−4 =8×10−11M
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