Q.
Molar conductivities Λm∘ at infinite dilution of NaCl, HCI and CH3COONa are 126.4,425.9 and 91.0 S cm2mol-1 respectively. Λm∘ for CH3COOH will be
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a
425.5 S cm2mol−1
b
180.5 S cm2 mol−1
c
290.85 S cm2 mol−1
d
390.5 S cm2 mol−1
answer is B.
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Detailed Solution
CH3COONa+HCl⟶NaCl+CH3COOHΛmCH3COOH∘=ΛmCH3COONa∘+Λm(HCl)∘−Λm(NaCl)0ΛmCH3COOH=(91.0+425.9−126.4)Scm2mol−1ΛmCH3COOH=390.5Scm2mol−1
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