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Q.

Molar mass of acetic acid  measured by osmotic pressure experiments is 75 grams. Degree of dimerization of acetic acid dissolved in benzene is

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a

0.4

b

0.5

c

0.6

d

0.3

answer is A.

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Detailed Solution

i=1-α+α2; i=1-α2........1 i=MnormalMabnormal; i=6075=45.....2 from 1 and 2 α2=15;  α=0.4;
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Molar mass of acetic acid  measured by osmotic pressure experiments is 75 grams. Degree of dimerization of acetic acid dissolved in benzene is