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The molar solubility of Ag2CO3 (ksp = 4x10-13 ) in 0.1M Na2CO3 solution is

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a

10-6

b

10-7

c

2x10-6

d

2x10-7

answer is A.

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Detailed Solution

Na2CO3 → 2Na+ + CO3-2 2×0.1M 0.1M Ag2CO3 → 2Ag+ + CO3-2 2s s+0.1 Ksp = (2s)2(s + 0.1) 4x10-13 = 4s2 x 0.1Neglecting s3 s2 = 10-12 s = 10-6

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