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Q.

1 mole of MnO42− in neutral aqueous medium disproportionates to

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a

23 mole of MnO4−and 13 mole of MnO2

b

13 mole of MnO4−and 23 mole of MnO2 .

c

13 mole of Mn2O7 and 13 mole of MnO2

d

23 mole of Mn2O7 and 13 mole of MnO2

answer is A.

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Detailed Solution

3 MnO42-+4 H+→2 MnO4-+MnO2+2 H2O3 moles MnO42-→2 moles  MnO4-+1 mole  MnO21 mole MnO42-→23  mole   MnO4-+13  mole  MnO2
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