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Q.

0.1 mole of N2O4(g) was sealed in a tube under one atmospheric conditions at 25oC. Calculate the number of moles of NO2(g) present, if the equilibrium N2O4(g)  ⇌  2NO2(g)  KP=0.14 is reached after some time

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a

1.8 × 102

b

2.8 × 102

c

0.034

d

2.8 × 10-2

answer is C.

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Detailed Solution

N2O40.1   ⇌    2NO200.1-α           2α∴   P ∝ 0.1If V and T are constants P ∝ 0.1 + αP=0.1 + α/0.1KP=2α20.1 - α × P0.1 + αor     KP=4 α20.1 - α=0.14 α=0.017NO2=0.017 × 2=0.034  mole
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0.1 mole of N2O4(g) was sealed in a tube under one atmospheric conditions at 25oC. Calculate the number of moles of NO2(g) present, if the equilibrium N2O4(g)  ⇌  2NO2(g)  KP=0.14 is reached after some time