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Q.

1 mole of urea is dissolved in 1 kg of each of solvent A, B,C and D seperately and different solutions are prepared.Boiling point order is Tq

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a

Kb of solvent A  is greater than Kb of solvent D

b

Kb of solvent D  is greater than Kb of solvent B

c

Kb of solvent A  is greater than Kb of solvent C

d

Kb of solvent C is greater than Kb of solvent A,B and D

answer is A.

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Detailed Solution

Tb = Tb0 + kb mSince Tb0  and m is same  higher the value of Tb, higher will be kb
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1 mole of urea is dissolved in 1 kg of each of solvent A, B,C and D seperately and different solutions are prepared.Boiling point order is Tq