Molecular formula of ‘A’ C8H8O . ‘A’ gives ppt with 2, 4 DNP. ‘A’ gives yellow crystals with NaOH+I2 . ‘A’ does not gives Tollen's (or) Fehling test. It neither ‘decolourise Br2 / H2O nor Baeyer’s reagent. On oxidation with chromic acid 'A' gives C7H6O2. A & B are
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a
C6H5CH2CHO, C6H5COOH
b
C6H5COCH3, C6H5COOH
c
C6H5CH2CHO, HCOOC6H5
d
C6H5COC3, HCOOC6H5
answer is B.
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Detailed Solution
So ‘A’ must be a saturated ketone containing -COCH3 group.The M.F suits C6H5 - CO - CH3 , Acetophenone ;
Molecular formula of ‘A’ C8H8O . ‘A’ gives ppt with 2, 4 DNP. ‘A’ gives yellow crystals with NaOH+I2 . ‘A’ does not gives Tollen's (or) Fehling test. It neither ‘decolourise Br2 / H2O nor Baeyer’s reagent. On oxidation with chromic acid 'A' gives C7H6O2. A & B are