A molecule ‘M’ associates in a given solvent according to the equation M⇌(M)n for a certain concentration of ‘M’ , the van't hoff factor was found to be 0.9 and the fraction of associated molecules was 0.2, the value of n is
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answer is 3.
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Detailed Solution
Let the degree of association be α M⇌(M)n Initially 1 0 After time t 1-α αnTotal moles after association = 1-α+αn=1+1n-1α i=moles after associationinitial moles=1+1n-1α1 i-1=1n-1; i=1-α+αn; By substituting i=0.9 , α=0.2 we get n=2