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Q.

The molecule which has T – shaped structure is

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a

PCl3

b

ClF3

c

NH3

d

BCl3

answer is B.

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Detailed Solution

ClF3 has sp3 d hybridisation. Out of five sp3 d hybrid orbitals two are completely filled by lp and three are half filled which overlap with three 2pz half filled orbitals of three F-atoms. Due to the presence of two lps its geometry is bent T-shaped.
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The molecule which has T – shaped structure is