3 moles of a diatomic gas are heated from 127°C to 727°C at a constant pressure of 1 atm. Entropy change is (log 2.5 = 0.4)
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a
- 22.98 JK-1
b
22.98 JK-1
c
57.4 JK-1
d
80.42 JK-1
answer is D.
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Detailed Solution
When temperature changes from T1 to T2 at constant pressure.ΔS=2.303nCplogT2T1n=3,Cp=T2R=3.5R for diatomic gas T1=400K,T2=1000KΔS=2.303×3×3.5×8.314log1000400=2.303×3×3.5×8.314(log2.5)=2.303×3×3.5×8.314×0.4JK−1=80.42JK−1