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Q.

2 moles of PCl5 was heated in a closed vessel of 2 litre capacity. At equilibrium, 40% of PCl5 is dissociated into PCl3 and Cl2. The value of equilibrium constant is

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a

0.266

b

0.53

c

2.66

d

5.3

answer is A.

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Detailed Solution

PCl5   ⇌   PCl3  +  Cl2Initially :     2                 0          0at euil. : 2 × 60100    2 × 40100  2 × 40100Volume of container = 2 LKC = 2 × 40100 × 2 × 2 × 40100 ×22 × 60100 ×2=0.266
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