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Q.

The most reactive compound towards electrophilic nitration is

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a

toluene

b

benzene

c

benzoic acid

d

nitrobenzene

answer is A.

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Detailed Solution

−CH3 is elemron-donating group (EDG) favours delocalisation effect and thus SE, at o and p-position.−NO2,−COOH are electron withdrawing groups (EWG) and deactivate benzene nucleus for SE reaction.
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