First slide
Reactive intermediates
Question

The most stable carbocation amongst the following is:

Moderate
Solution

→ Bridge head carbocation is highly unstable

Reason, the bridge head carbocation unable to acquires the planarity [120o] , and hence it is highly unstable.

As the no. of +IE groups [alkyl groups] increases,

sharing of positive charge by no of carbon atoms increases,

i.e., charge distribution among the atoms increases,

hence stability of carbocation increases.

Hint:

sharing increases,

caring increases,

stability increases.

E.g:

                                                       

 

"H" is neither +IE nor –IE group                                      Here  "CH3" group acts as +IE group

+ve cahrge located only on single carbon                   

+ve charge is shared among the 4-carbon atoms

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