In a multi-electron atom, which of the following orbitals described by the three quantum numbers will have the same energy in the absence of magnetic field(i) n = 1, l = 0, m = 0 (ii) n = 2, l = 0, m = 0 (iii) n = 2, l = 1, m = 1 (iv) n = 3, l = 2, m = 1 (v) n = 3, l = 2, m = 0
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a
(i) and (ii)
b
(ii) and (iii)
c
(iii) and (iv)
d
(iv) and (v)
answer is D.
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Detailed Solution
Orbitals having (n + l) same possess same energy in absence of magnetic field.