Q.

N3−→(I)NO2→(II)NO3−    .What will be the n-factor in step(I) and in step(II)?

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a

13 , 1

b

13 ,  2

c

11 ,  5

d

13 , 3

answer is A.

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Detailed Solution

N3−(−13)→(I)NO2(+4)→(II)NO3−(+5) Change in the oxidation state of nitrogen from azide to nitrogen dioxide is  ( 4 + 1/3)×3 =13, hence  n-factor = 13       Change in the oxidation state of nitrogen from  nitrogen dioxide to Nitrate is +1, hence n- factor =1
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