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Q.

20% of N2O4 molecules are dissociated in a sample of gas at 27ºC and 760 torr. Mixture has the density at equilibrium equal to

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a

1.48 g/L

b

1.84 g/L

c

2.25 g/L

d

3.12 g/L

answer is D.

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Detailed Solution

Degree of decomposition, α =M-mmn-1M = MW of undissociated speciesm = MW of equilibrium mixture (observed molecular weight)n = number of particles produced by the dissociation of one moleculeN2O4(g) ⇌2NO2(g)n = 2α = 0.2T = (27 + 273)KP = 760 torr (or) 1 atmObserved molecular weight = 76.66for an ideal gas, density (d)
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