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Q.

For NaCl, lattice energy = - 186 kcal/mol, the solvation energy of Na+  and  Cl−  are  −97  and  −85 kcal/mole respectively. Therefore for NaCl (s)

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a

enthalpy of solution is exothermic and magnitude equal to 4 kcal/mol

b

enthalpy of solution is exothermic and magnitude equal to 368 kcal/mol

c

enthalpy of solution is endothermic and magnitude equal to 4 kcal/mol

d

enthalpy of solution is endothermic and magnitude equal to 368 kcal/mol

answer is C.

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Detailed Solution

Lattice energy or Breaking energy is + 186 kcal/moleΔHsolv  =−97−85=−182  kcal/mol−LE=+186  kcal/molΔHsolution  =+186−182=4   kcal/mol &  endothermic.
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