Q.

NH3 gas is liquefied more easily than N2. Hence,

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a

van der waals' constants a and b of NH3 > that of N2

b

van der waals' constant a and b of NH3 < that of N2

c

aNH3>aN2 but bNH3

d

aNH3bN2

answer is A.

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Detailed Solution

If a gas is liquefied, it means volume is decreased and attractive force exists. a is a measure of attractive force and b the co-volume hence,aNH3>aN2 and bNH3>bN2
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