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Questions  

Nickel (Z = 28) combines with a uninegative monodentate ligand X- to form a paramagnetic complex [NiX4]2-. The number of unpaired electron(s) in the nickel and geometry of this complex ion are, respectively:

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By Expert Faculty of Sri Chaitanya
a
One, tetrahedral
b
Two, tetrahedral
c
One, square planar
d
Two, square planar

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detailed solution

Correct option is B

If X- is weak field ligand (say Cl-) then NiCl42− is tetrahedral (sp3) with two unpaired electrons. If X- is strong field ligand (say CN-), then NiCN42− is square planar (dsp2) with no unpaired electron. Also given NiX42− is paramagnetic.


Similar Questions

Among NiCO4,NiCN42,NiCl42 species, the hybridization states at the Ni atom are, respectively

(At. no. of Ni = 28)

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