Q.

Nickel (Z = 28) combines with a uninegative monodentate ligand X- to form a paramagnetic complex [NiX4]2-. The number of unpaired electron(s) in the nickel and geometry of this complex ion are, respectively:

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a

One, tetrahedral

b

Two, tetrahedral

c

One, square planar

d

Two, square planar

answer is B.

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Detailed Solution

If X- is weak field ligand (say Cl-) then NiCl42− is tetrahedral (sp3) with two unpaired electrons. If X- is strong field ligand (say CN-), then NiCN42− is square planar (dsp2) with no unpaired electron. Also given NiX42− is paramagnetic.
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