A nitrogen containing compound dissolves in 10% aqueous sulphuric acid. The Hinsberg test (C6H5SO2Cl in base) gives a solid product that is not soluble in 10% aqueous NaOH. Which of the following would best fit in these facts?
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a
N, N-dimethylaniline,
b
N-methylbenzamide
c
Benzylamine,
d
N-methylaniline,
answer is D.
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Detailed Solution
These are the characteristics of secondary amines and C6H5NHCH3 is a secondary amine.
A nitrogen containing compound dissolves in 10% aqueous sulphuric acid. The Hinsberg test (C6H5SO2Cl in base) gives a solid product that is not soluble in 10% aqueous NaOH. Which of the following would best fit in these facts?