Q.

A nitrogen-hydrogen mixture initially in the molar ratio of 1 : 3 reached equilibrium to form ammonia when 25% of the N, and H, had reacted. If the total pressure of the system was 21atm, the partial pressure of ammonia at the equilibrium was

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a

4.5 atm

b

3.0 atm

c

2.0 atm

d

1.5 atm

answer is B.

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Detailed Solution

N2(g)+3H2(g)⇌2NH3(g) t=0,    1         3                0 teq. ;    1-x    3-3x        2x                   given, x=1/4 PNH3 =XGas ·PTotal          =0.53.5×21=3atm
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