Q.

NO2  and  N2O4 are two forms of nitrogen dioxide. One exists in gaseous state while other in liquid state. The nature of NO2  and  N2O4 forms are

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a

both are paramagnetic

b

both are diamagnetic

c

NO2 is paramagnetic while N2O4 is diamagnetic

d

NO2 is diamagnetic while N2O4 is paramagnetic

answer is C.

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Detailed Solution

NO2 is an odd electron molecule (paramagnetic) The dimer, N2O4 has no unpaired electron.(diamagnetic)
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NO2  and  N2O4 are two forms of nitrogen dioxide. One exists in gaseous state while other in liquid state. The nature of NO2  and  N2O4 forms are