28 NO3− + 3As2S3 + 4H2O → 6AsO43−+28NO+9SO42−+8H+.What will be the equivalent mass of As2S3 in above reaction : (Molecular mass of As2S3 = M)?
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a
M2
b
M4
c
M24
d
M28
answer is D.
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Detailed Solution
From the given equation , As+32S-23→As+5O4-3 + S+6O4-2 Change in oxidation state of ‘As’ = 2(2) =4 Change in oxidation state of ‘S’ = 3(8) = 24Total change in oxidation state = n-factor = 24+4=28∴ Equivalent weight of As2S3 = M28Where M= molecular mass