Questions
For the non-stoichiometric reaction , the following kinetic data were obtained in three separate experiments, all at 298 K.
Initial concentration [A] | Initial concentration [B] | Initial rate of formation of C (mol L-1s-1) |
0.1 M | 0.1 M | |
0.1 M | 0.2 M | |
0.2 M | 0.1 M |
The rate law for the formation of C is
detailed solution
Correct option is D
This problem can be solved by determining the order of reaction with respect to each reactant and then writing rate law equation of the given equation accordingly as,R=dCdt=k[A]x[B]ywhere, x = order of reaction w.r.t A y = order of reaction w.r.t B 1.2×10−3=k(0.1)x(0.1)y1.2×10−3=k(0.1)x(0.2)y2.4×10−3=k(0.2)x(0.1)yor R=k[A]1[B]0Similar Questions
Following data is given for the reaction,
Experiment | Initial rate | ||
I | |||
II | |||
III |
The order of reaction with respect to X and Y respectively are
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