A non-volatile solute (A) is dissolved in a volatile solvent (B). The vapour pressure of resultant solution is Ps. The vapour pressure of pure solvent is P0B. If "X" is mole fraction, which of the following is correct?
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a
PS = PB0 . XA
b
PB0 = PS XB
c
PS = PB0 . XB
d
PB0 = PS XA
answer is C.
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Detailed Solution
Given = V.P of pure solvent Ps= V.P of a solution of non-volatile solute XA= mole fraction of solute XB = mole fraction of solventRaoult's law states that " V.P of a solvent in a solution of non-volatile solute isdirectly proportional to its mole fraction in the solution" For a pure solvent substitute the value of K in eq (1)