Q.
The number of correct options is (a) I ⊖>Br⊖>Cl⊖>F⊖ (polarisability) (b) Li⊕>Na⊕>K⊕>Rb⊕ (polarisation power) (c) H2O>H2S>H2Se>H2 Te (order of b.pt.) (d) H2⊖
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answer is 3.
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Detailed Solution
(a), (b) and (d) are correct options.(a) I⊖>Br⊖>Cl⊖>F (Polarisability).According to Fajan's rule, large anion is more polarisable.(b) Li⊕>Na⊕>K⊕>Rb⊕ (Polarisation power).According to Fajan's rule, small cation is more polarisable.(c) Wrong. Boiling point order is(d) Both H2⊖ and H2⊕ have same bond order of 0.5. H2⊕ is more stable than H2⊖, since H2⊕contains one e- in bonding orbitals whereas H2⊖ contains one e- in antibonding orbitals.
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