Number of moles of KMnO4 required to oxidize one mole of FeC2O4 in acidic medium is
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a
0.6
b
0.167
c
0.2
d
0.4
answer is A.
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Detailed Solution
eq. of KMnO4=eq. of FeC2O4n×Valency factor=n×Valency factorx × 5=1 × 3x=0.6 Note: Mn +7O4-+Fe+2+C+32O4-2→H+Mn+2+Fe+3+C+4O2 Change in oxidation state of Mn =valency factor =5 Change in oxidation state in Fe(C2O4)=valency factor=1+2(1)=3