The number of moles of KMnO4 that will be needed to react completely with one mole of ferrous oxalate in acidic solution is
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a
3/5
b
2/5
c
4/5
d
1
answer is A.
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Detailed Solution
KMnO4 : n-factor in acidic medium =5 FeC2O4 : n-factor = 3 MnO4-→Mn+2Fe+2→Fe+3;C2O4-2→2CO2 criss-cross method3 moles of KMnO4 oxidizes 5 moles of FeC2O4 X moles of KMnO4 oxidizes 1 moles of FeC2O4 X = 3/5