Number of moles of MnO4- required to oxidize one mole of ferrous oxalate completely in acidic medium will be
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a
7.5 moles
b
0.2 moles
c
0.6 moles
d
0.4 moles
answer is C.
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Detailed Solution
In acidic medium MnO4- oxidises ferrous oxalate as follows :2MnO4-+5C2O4-2+16H+→2Mn2++10CO2+8H2O∵ 5 moles of oxalate ions are oxidised by 2 moles of MnO4-.∴ 1 mole of oxalate ion is oxidised by=25mole ofMnO4-=0.4moles