Q.

At 35oC the vapour of pure chloroform is 0.359 atm and that of pure acetone is 0.453 atm. A solution containing 1 mole of chloroform and 4 mole of acetone has a vapour pressure of (in atm)

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a

0.400

b

0.812

c

0.094

d

0.434

answer is D.

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Detailed Solution

P=PAoXA+PBoXB=0.359×15+0.453×45=15(0.359+1.812)=0.434
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At 35oC the vapour of pure chloroform is 0.359 atm and that of pure acetone is 0.453 atm. A solution containing 1 mole of chloroform and 4 mole of acetone has a vapour pressure of (in atm)