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Q.

For octahedral complex, which of the following dn configurations of metal cation cannot exist in high spin and low spin forms ?

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a

d3 and d8

b

d3 and d5

c

d3 and d6

d

d4 and d8

answer is A.

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Detailed Solution

In d3 and d8 octahedral complexes number of unpaired e-s at central metal atom,/ion never changes, therefore for such octahedral complexes terms high spin and low spin not used.
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