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Q.

Oil paintings is blackened by atmospheric H2S due to the formation of X, H2O2, changes X to colourless (white) Y. X and Y respectively are

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a

PbS and PbSO3

b

PbS and PbSO4

c

PbS and PbO

d

PbS and PbO2

answer is B.

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Detailed Solution

Oil paints contain Pb2+ in the form of CH3COO2Pb. In contact with atmospheric H2S, it is blackened due to the formation of PbS(X) .PbS can be cleaned by H2O2, which changes PbS to PbSO4, (Y)CH3COO2Pb(In oil paint) +H2S→PbSBlack  x+2CH3COOHPbS+4H2O2→PbSO4white  Y+H2O
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