Q.

one of the following reactions proceeds through free radical chain mechanism?

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a

Hydrolysis of  3° butyl chloride with aq.KOH

b

Photochemical chlorination of methane

c

Addition of HBr to ethane

d

Addition of NaHSO3 to Acetone

answer is B.

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Detailed Solution

Cl−Cl→ hν2Cl•CH4+C l·→CH3Cl+H·
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