Q.

One mole of CaOCl2 is dissolved in water and excess of KI added. Hypo Na2S2O3 required to react with the oxidized part completely is

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a

1 mole

b

2.0 moles

c

1.5 moles

d

2.5 moles

answer is B.

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Detailed Solution

CaOCl2 + H2O  →  CaOH2 + Cl21 mol                                                1 molCl2 + 2KI  →   2KCl  +  I2                                         1 moleI2 + KI   ⇌   KI3 I2 in KI + 2Na2S2O3 →  2NaI  + Na2S4O6
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