Q.

One mole of ice is converted in to water at 273K. The entropies of H2O(s) and H2O(l) are 38.20 and 60.01 J mole-1K-1 respectively. The enthalpy change for this conversion is

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a

595.4 J mol-1

b

59.54 J mol-1

c

320.6 J mol-1

d

5954 J mol-1

answer is D.

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Detailed Solution

= 273 X 21.81 = 5954J
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One mole of ice is converted in to water at 273K. The entropies of H2O(s) and H2O(l) are 38.20 and 60.01 J mole-1K-1 respectively. The enthalpy change for this conversion is