Q.

One mole of a solute A is dissolved in a given volume of a solvent. The association of the solute take place as follows: nA⇌AnIf α is the degree of association of A, the van't Hoff factor i is expressed as:

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a

i=1−α

b

i=1+αn

c

i=1−α+αn1

d

i=1

answer is C.

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Detailed Solution

i=C(1−α)+CαnC⇒i=1−α+αn
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One mole of a solute A is dissolved in a given volume of a solvent. The association of the solute take place as follows: nA⇌AnIf α is the degree of association of A, the van't Hoff factor i is expressed as: